Tuesday, 5 June 2018

1:18 PM

Machine generated alternative text:
L5: PV diagrams 
PV = nRT A Eint Q + W 
Isovolumetric constant volume 
constant 
AEint — Q nCvAT 
Isobaric constant pressure 
a constant 
Q = nCpAT 
Isothermal constant temperature 
PV = constant 
AEtnt 
Adiabatic process no heat transfer 
P VI = constant

 

Machine generated alternative text:
Remember: 
PV = nRT 
Isothermal 
AP = 0 
w=pnv 
PdV 
Const. temperature 
AT=O 
AE -O Q = -W 
nRT 
nRT 
Adiabatic 
No heat exchange 
P, V and T are 
changing 
T decrease with P 
and V increase 
Note: can be a fast 
process 
Special case: Adiabatic 
free expansion is 
expansion into a 
vacuum, then its 
isothermal and 
Isobaric 
Constant pressure 
PdV 
= Q+ pnv 
T increase with V 
increase 
Isovolumetric 
(Isochoric) 
Constant Volume 
AV=O 
AEint = Q 
T increase with P 
increase 
w 
W 
—nRT 
U) 
Thor—m. 
Isobaric 
+48 
Volume

 

 

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